Volume 314
Main Index

Issues 1-2, Pages 1-246 (21 October 1986)

Insertion reactions of a tungsten hydride complex Pages C31-C33 Peter Kundel, Heinz Berke

Why is the η1-C coordination mode preferred for CO2 in [Co(N,N′-ethylenebis(salicydeneaminato))(CO2)]−? an ab-initio MO study Pages C63-C67 S. Sakaki, A. Dedieu

[(C5H5)4FeNi](BF4)2; ein charge-transfer-komplex aus elektronenreichen und elektronenarmen metallocen-fragmenten Pages C39-C42 Norbert Kuhn, Hans Schumann

Verschiedene strukturen von β-diketonderivaten des quecksilbers Pages C1-C4 Wulf Depmeier, Klaus Dietrich, Klaus König, Hans Musso, Willy Weiss

Iron-molybdenum and iron-tungsten sulphido clusters containing hydrazido(2 −) ligands Pages C25-C26 J. R. Dilworth, S. Morton

Author index Pages C71-C72

Preparation and reactions of trihalogeno(pentamethylcyclopentadienyl)ruthenium(IV) Pages C46-C48 Noriaki Oshima, Hiroharu Suzuki, Yoshihiko Moro-oka, Hideo Nagashima and, Kenji Itoh

The Industrial Uses of Tin Chemicals, : by S.J. Blunden, D.A. Cusack, and R. Hill, The Royal Society of Chemistry, 1985, vi + 337 pages, £26.00; US$ 38.00. ISBN 0-85186-927-0. Page C68 Colin Eaborn

Pseudohalogenometallverbindungen : LXVI. Darstellung und struktur von trans-difulminato-bis(triphenylphosphan)platin(II), (Ph3P)2Pt(CNO)2 Pages C55-C58 Wolfgang Weigand, Ulrich Nagel, Wolfgang Beck

The novel formation of an acetone enolate complex via the addition of methyllithium to the acylrhodium(I) compound Rh(COMe)(CO)(triphos) (triphos = MeC(CH2PPh2)3) Pages C51-C54 Gregory G. Johnston, Michael C. Baird

Metallocen-chalcogen-verbindungen: Eine einfache synthese von [(η-C5H4R)2ZrTe]2 komplexen mit einem planaren metallacyclischen vierringgerüst Pages C21-C24 Gerhard Erker, Thomas Mühlenbernd, Rainer Nolte, Jeffrey L. Petersen, Gerard Tainturier and, Bernard Gautheron

Potassium selective metallocene cryptand molecules Pages C9-C11 Paul D. Beer, Christopher G. Crane, Anthony D. Keefe, Andrew R. Whyman

Dynamic stereochemistry of the TiBr + Sph− → TiSPh, conversion with isocyanato complexes of titanocene Pages C12-C16 J. Besançon, J. Tirouflet, B. Trimaille, Y. Dusausoy

A mild phase transfer synthesis of the μ-methylenebis-(tetracarbonyliron) complex μ-CH2Fe2(CO)8 from iron pentacarbonyl and dibromomethane Pages C43-C45 Guy Tanguy, Jean-Claude Clement, Hervé des Abbayes

Announcement Page C69

Funktionelle trimethylphosphinderivative : XXV. Ein tri-spirocyclischer organoaluminiumphosphannickel(0)-komplex Pages C5-C8 Hans Heinz Karsch, Armin Appelt

Catalysis of the water gas shift reaction by a Ru3(CO)12-2,2′-bipyridine complex Pages C49-C50 Tapani Venäiläinen, Tapani A. Pakkanen, Tuula T. Pakkanen, Eero Iiskola

Réaction d'insertion de co dans un complexe μ-alkylidénique du fer: Piégeage de dérivés acylés Pages C34-C38 D. Navarre, H. Rudler, J. C. Daran

Electrochemical studies on organometallic compounds : XIV. Electrogeneration of the bis(phenylethynyl)dicyclopentadienyltitanium(III) anion Pages C17-C20 L. Koch, A. Fakhr, Y. Mugnier, L. Roullier, C. Moise, E. Laviron

Novel diethylamino migrations in the reaction of diethylaminodichlorophosphine with sodium tetracarbonylferrate(−II) Pages C27-C30 R. B. King, F. -J. Wu, E. M. Holt

Cyclometallierende photodecarboxylierung von cobalt(III)-komplexen mit 1-diethylentriaminmono-3-propionat Pages C59-C62 A. L. Poznjak, V. I. Pawlowski, L. M. Schkolnikowa, N. M. Djatlowa and, A. B. Iljuchin

Bicyclic silanes from cyclosilane-metal derivatives Pages 1-5 F. K. Mitter, G. I. Pollhammer, E. Hengge

Darstellung und charakterisierung von bis(η5-cyclopentadienyl)titan- und -zirconium-anthracen Pages 7-11 Joachim Scholz, Karl-Heinz Thiele

The vibrational spectrum of (bromomethyl)mercury(II) bromide Pages 13-17 H. G. M. Edwards

Derives mono et bicycliques du bore tetracoordonne et des α-aminodiacides: reactions avec divers nucleophiles Pages 19-24 Bernard Garrigues, Michel Mulliez

Siliciumverbindungen mit starken intramolekularen sterischen wechselwirkungen : XXVI. Neuartige sechsringe durch photolyse von hexa-t-butylcyclotrisilan in gegenwart von nitrilen Pages 25-32 Manfred Weidenbruch, Annemarie Schäfer, Karl Peters and, Hans Georg Von Schnering

N-halogensiyl-phosphinimine; ein neuartiger chlor-fluor-austausch Pages 33-38 U. Kliebisch, U. Klingebiel

Zur synthese von siloxanen : IV. Acetolyse der konfigurationsisomere des 1-chlor-1,3,5-trimethyl-3,5-bis(trimethylsiloxy)cyclotrisiloxans Pages 39-45 U. Scheim, K. Rühlmann, H. Grosse-Ruyken, A. Porzel

Regiodefined synthesis of α-bromo, α-phenylthio, and α-phenylseleno ketones by means of specific substitution of the trimethylsilyl group in α-trimethylsilyl ketones Pages 47-52 Isamu Matsuda, Susumu Sato

Carbon---carbon and carbon---chalcogen spin---spin coupling constants in chalcogen-substituted acetylenes Pages 53-60 K. Kamieska-Trela, Z. Biedrzycka, R. Machinek, B. Knieriem and, W. Lüttke

OLefin metathesis of alkenylsilanes : II. On the initiation of olefin metathesis with organosilanes Pages 61-73 Mats Berglund, Carlaxel Andersson, Ragnar Larsson

Synthese silylierter enamine durch rhodium-katalysierte hydrosilylierung von 1-aza- und 1,4-diaza-1,3-dienen Pages 75-83 Monika Brockmann, Heindirk tom Dieck

The x-ray structure of (O-isopropyldithiocarbonato)triphenyltin(IV); an example of S- and O-xanthate coordination Pages 85-89 Edward R. T. Tiekink, George Winter

Übergangsmetall-komplexe miet schwefelliganden : XXI. Thiolato-amin-komplexe von eisen(II) und molybdän(II) mit [M(SNNS)]-einheiten und CO-, PMe3-, NO- sowie N2H4-koliganden (SNNS = (SC6H4N(R)C2H4N(R)C6H4S)2−, R = H, CH3) Pages 91-103 Dieter Sellmann, Ulrich Reineke

Zweikernige dicyclopentadienyltitan-komplexe mit sauerstoff-brücke. die struktur von [Cp2Ti]2(μ-O) Pages 105-111 Brigette Honold, Ulf Thewalt, Max Herberhold and, Helmut G. Alt, Lawrence B. Kool and, Marvin D. Rausch

Organotitanium chemistry : V. electron impact and negative ion chemical ionization mass spectra of derivatives of dicyclopentadienyltitanium(IV) dichloride and allyldicyclopentadienyltitanium(III) Pages 113-122 Guixiang Fu, Yanlong Qian, Yongzhen Xu, Shoushan Chen

Bildung eines neuartigen (η-1,3-butadienyl)niob-komplexes durch reaktion von 2-butin mit bis(η-cyclopentadienyl)-niobtrihydrid: systheses, kristall- und molekülstruktur von bis(η-cyclopentadienyl) [1,3,4-η3-(1,2,3,4- tetramethyl-1,3-butadienyl)]niob Pages 123-130 G. E. Herberich, B. Hessner, H. Mayer

Phenoxotantalum(V) Complexes Pages 131-138 M. Gómez, P. Royo, J. M. Selas

Reaction of the alkylidyne complex [W(CR)(CO)2(η-C5H5)] with PHPh2. Synthesis and X-ray structures of the complexes [Ph2)(CO)2(η-C5H5)] and [Ph2(PHPh2)(CO)(η-C5H5)] (R = C6H4Me-4) Pages 139-149 G. A. Carriedo, V. Riera, M. Luz Rodriguez, J. C. Jeffery

Mehrfachbindungen zwischen hauptgruppenelementen und übergangsmetallen : XXXI. Über ein- und zweikernige halogenorhenium(V)-komplexe: synthesen und strukturen Pages 151-162 Wolfgang A. Herrmann, Ulrich Küsthardt, Martina Flöel, Jürgen Kulpe, Eberhardt Herdtweck, Erdmuthe Voss

2,6-Dimethylphenyl (“xylyl”) isocyanide complexes or iron: preparation and crystal and molecular structures of trans-dichlorotetrakis(xylyl isocyanide)iron(II), [FeCl2(2,6-Me2C6H3NC)4] and chloropentakis(xylyl isocyanide)iron(II) tetrachloroferrate(III), [FeCl(2,6-Me2C6H3NC)5][FeCl4] Pages 163-172 Michael G. B. Drew, George H. Dodd, Jacqueline M. Williamson, Gerald R. Willey

Complexes binucleaires de fer carbonyle liaison σ-metal-carbone: Synthese, etude structurale et proprietes Pages 173-184 Henri Patin, Boguslaw Misterkiewicz, Jean-Yves Le Marouille and, Abdelhamid Mousser

Chemistry of bridged carboxylate ruthenium complexes. Crystal structures of [Ru(PhCOO)(CO)2(PhCOOH]2, [Ru(4-FC6H4COO)2(CO)5(H2O)]2·0.5 C6H6, and [Ru2(-BuCO2)2(CO)4(-BuCO2H)]2 Pages 185-212 Michal Rotem, Israel Goldberg, Uri Shmueli, Youval Shvo

Cyclopentadienyl-ruthenium and -osmium chemistry : XXVII. X-ray structures of Ru(CCPh)(dppe)(η-C5H5) and of [Ru(L)(PPh3)2(η-C5H5)]X (L = C(OMe)Et, X = PF6; L = C=CMePh, X = I) Pages 213-225 Michael I. Bruce, Mark G. Humphrey, Michael R. Snow, Edward R. T. Tiekink

Synergistic effect on homogeneous ruthenium-rhodium catalysts for methanol homologation Pages 227-230 Jouni Pursiainen, Kauko Karjalainen, Tapani A. Pakkanen

Rhodium-ctalyzed C---C coupling of 1,3-dienes with 3-alkenoic acids Pages 231-239 Giuseppe Salerno, Francesco Gigliotti, Gian Paolo Chiusoli

trans-bis(diphenylphosphine)cyclopropane; a ligand selective for binuclear complexation with ca. 4.5 Å intermetallic separation Pages 241-246 John M. Brown, Andrew R. Lucy

Issue 3, Pages 247-383 (28 October 1986)

Unexpected direct formation of a bridging 4-cyanobuta-1,3-dienylidene group from reaction of [(C5H5)Fe(CO)]2(μ-C=CH2) with HCCCN Pages C81-C84 Michel Etienne, Jacques E. Guerchais

Electron-rich, hydrocarbon-metal complexes: Synthesis and oxidation properties of bis(η3-allyl) iron complexes containing basic phosphines Pages C76-C80 Jean-Michel Grosselin, Pierre H. Dixneuf

Author index Pages C85-C86

Subject index Pages C87-C92

Reversal of regiocontrol in the alkylation of an arene π-complex Pages C73-C75 Rikki P. Alexander, G. Richard Stephenson

Die chemie der schweren carben-analogen R2M, M = Si, Ge, Sn : X. 7-sila-norbornadiene: reaktionen mit halogenen und thermolyse in genewart von metallorganischen oder organischen halogeniden Pages 247-259 Hubertus Appler, Wilhelm P. Neumann

Die chemie der schweren carben-analogen R2M, M = Si, Ge, Sn : XI. Reaktionen von thermisch erzeugten dimethylsilylen mit C---C-mehrfachbindungen Pages 261-271 Hubertus Appler, Wilhelm P. Neumann

Bis(diphenylphosphino)acetylene complexes of Cp(CO)2Mn and (CO)5M(M = Cr, W) Pages 273-279 Olli Orama

Tetracarbonyl(carbene-phosphine) and tetracarbonyl(imidate-phospine) complexes of chromium(0) Pages 281-294 Helgard. G. Raubenheimer, Gert. J. Kruger, Hendrick W. Viljoen, Simon Lotz

Mehrfachbindungen zwischen hauptgruppenelementen und übergangsmetallen : XXXII. Insertions- und metathesereaktionen von metallorganischen eisen-selen-komplexen Pages 295-305 Wolfgang A. Herrmann, Jürgen Rohrmann, Eberhardt Herdtweck, Christian Hecht, Manfred L. Ziegler and, Orhan Serhadli

Syntheses of μ3-η2 phosphaalkyne; complexes of trinuclear iron and ruthenium hydridononacarbonyl anions [M3H(CO)9(ButCP)]− (M = Fe, Ru) Pages 307-310 Mohamed F. Meidine, John F. Nixon, René Mathieu

Cluster chemistry : XXXXVIII. Some reactions of Ru3(CO)12 with nitrogen heterocycles. X-ray crystal structures of Ru3(μ-CO)2(CO)8(bipy) and Ru3(μ-H){μ-N2C3H(CF3)2-3,5}(CO)10 Pages 311-322 Michael I. Bruce, Mark G. Humphrey, Michael R. Snow, Edward R. T. Tiekink, Robert C. Wallis

Cluster chemistry : IL. Further examples of ruthenium and osmium cluster carbonyls containing the olefinic tertiary phosphine PPh2(C6H4CH=CH2-2) (sp): x-ray structure of Os3H(μ-H)(CO)10(sp) Pages 323-331 Michael I. Bruce, Michael L. Williams

The addition of small molecules to (η-C5H5)2Rh2(CO)(CF3C2CF3) : IV. The sunlight assisted making and breaking of alkene C---H bonds on the dirhodium centre; the crystal and molecular structures of (η-C5H5)2Rh2(CH=CHCN){C(CF3)=CF3)H} · H2O and (η-C5H5)2Rh2(CH=CF2){C(CF3)=C(CF3)H} Pages 333-355 Ron S. Dickson, Gary D. Fallon, Susan M. Jenkins, Brian W. Skelton and, Allan H. White

Studies on binuclear complexes. : The synthesis and molecular structure of PdMo(μ-Ph2-Ppy)2(μ-CO)(CO)2 · 0.5CH2Cl2 Pages 357-367 Zheng-Zhi Zhang, Hsu-Kun Wang, Hung-Gen Wang and, Ru-Ji Wang

Metals in organic syntheses : XIV. NMR, IR, and reactivity studies on the olefin hydroformylation catalyzed by Pt-Sn complexes Pages 369-383 Alberto Scrivanti, Adriano Berton, Luigi Toniolo, Carlo Botteghi